|
|
fatty_acid + [acyl-carrier_protein] + ATP <=> palmitoyl-[acyl-carrier_protein] + AMP + diphosphate
|
6.2.1.20
long-chain-fatty-acid---[acyl-carrier-protein] ligase
|
–
|
MK
|
|
BRENDA:
BR72;
BS211;
BS214
KEGG:
R01406
MetaCyc:
ACYLACPSYNTH-RXN;
RXN-13267;
RXN-13268
|
|
|
|
palmitoyl-[acyl-carrier_protein] + H2O <=> fatty_acid + [acyl-carrier_protein] + H+
|
2.3.1.85
fatty-acid synthase system
3.1.2.14
oleoyl-[acyl-carrier-protein] hydrolase
3.1.2.21
dodecanoyl-[acyl-carrier-protein] hydrolase
|
–
–
–
|
BMK
|
|
BRENDA:
BS12701;
BS364432;
BS382837;
BS432386
KEGG:
R01706;
R08163;
R12329
MetaCyc:
RXN-17108;
RXN-7902;
RXN-9548;
RXN-9549
|
|
|
|
palmitoyl-[acyl-carrier_protein] + sn-glycerol_3-phosphate <=> 1-palmitoyl-sn-glycerol_3-phosphate + [acyl-carrier_protein]
|
2.3.1.15
glycerol-3-phosphate 1-O-acyltransferase
|
–
|
|
|
BRENDA:
BS320530
MetaCyc:
RXN-17018
SABIO-RK:
11371
|
|
|
|
palmitoyl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] + H+ <=> 3-oxooctadecanoyl-[acyl-carrier_protein] + CO2 + [acyl-carrier_protein]
|
2.3.1
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
2.3.1.199
very-long-chain 3-oxoacyl-CoA synthase
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
|
–
–
–
–
|
MK
|
|
BRENDA:
BS320874;
BS377477
KEGG:
R07762
MetaCyc:
RXN-9632
SABIO-RK:
11307
|
|
|
|
hexadecanal + [acyl-carrier_protein] + NADP+ <=> palmitoyl-[acyl-carrier_protein] + NADPH + H+
|
1.2.1.50
long-chain acyl-protein thioester reductase
1.2.1.80
long-chain acyl-[acyl-carrier-protein] reductase
|
–
–
|
M
|
|
BRENDA:
BS426898
MetaCyc:
RXN-11706
|
|
|
|
palmitoyl-[acyl-carrier_protein] + CoA <=> palmitoyl-CoA + [acyl-carrier_protein]
|
2.3.1
2.3.1.85
fatty-acid synthase system
2.3.1.86
fatty-acyl-CoA synthase system
|
–
–
–
|
MK
|
|
BRENDA:
BS456174
KEGG:
R10700
MetaCyc:
RXN3O-9780
|
|
|
|
palmitoyl-[acyl-carrier_protein] + 2 reduced_ferredoxin_[iron-sulfur]_cluster + O2 + 2 H+ <=> (4Z)-hexadec-4-enoyl-[acyl-carrier_protein] + 2 oxidized_ferredoxin + 2 H2O
|
1.14.19.11
acyl-[acyl-carrier-protein] 4-desaturase
|
–
|
|
|
BRENDA:
BR51361
KEGG:
R11108
|
|
|
|
palmitoyl-[acyl-carrier_protein] + O2 + reduced_ferredoxin_[iron-sulfur]_cluster + H+ <=> (6Z)-hexadec-6-enoyl-[acyl-carrier_protein] + H2O + oxidized_ferredoxin
|
1.14.19.26
acyl-[acyl-carrier-protein] 6-desaturase
|
–
|
M
|
|
BRENDA:
BR51373
KEGG:
R11109
MetaCyc:
RXN-8388
|
|
|
|
palmitoyl-[acyl-carrier_protein] + reduced_ferredoxin_[iron-sulfur]_cluster + O2 + H+ <=> palmitoleoyl-[acyl-carrier_protein] + oxidized_ferredoxin + H2O
|
1.14.19.2
stearoyl-[acyl-carrier-protein] 9-desaturase
|
–
|
MK
|
|
KEGG:
R08161
MetaCyc:
RXN-8389
|
|
|
|
palmitoyl-[acyl-carrier_protein] + NADP+ <=> trans-Hexadec-2-enoyl-[acp] + NADPH + H+
|
1.3.1
1.3.1.10
enoyl-[acyl-carrier-protein] reductase (NADPH, Si-specific)
1.3.1.104
enoyl-[acyl-carrier-protein] reductase (NADPH)
1.3.1.39
enoyl-[acyl-carrier-protein] reductase (NADPH, Re-specific)
2.3.1.85
fatty-acid synthase system
2.3.1.86
fatty-acyl-CoA synthase system
|
–
–
–
–
–
–
|
K
|
|
KEGG:
R04970
MetaCyc:
RXN-9542
|
|
|
|
palmitoyl-[acyl-carrier_protein] + NAD+ <=> trans-Hexadec-2-enoyl-[acp] + NADH + H+
|
1.3.1.9
enoyl-[acyl-carrier-protein] reductase (NADH)
2.3.1
|
–
–
|
MK
|
|
KEGG:
R04969
MetaCyc:
RXN-9663
|
|
|
|
palmitoyl-[acyl-carrier_protein] + phosphate <=> hexadecanoyl_phosphate + [acyl-carrier_protein]
|
2.3.1.274
phosphate acyltransferase
|
–
|
|
|
BRENDA:
BS445544
SABIO-RK:
12851
|
|
|
|
palmitoyl-[acyl-carrier_protein] + H._pylori_KDO2-lipid_IVA <=> Stearoyl-KDO2-lipid_IVA + [acyl-carrier_protein]
|
2.3.1
|
–
|
K
|
|
KEGG:
R12193
|
|
|
|
palmitoyl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] + H+ <=> long-chain_3-oxoacyl-[acp] + CO2 + [acyl-carrier_protein]
|
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
|
–
|
|
|
MetaCyc:
2.3.1.41-RXN
|
|
|
|
hexadecanal + [acyl-carrier_protein] + NAD+ <=> palmitoyl-[acyl-carrier_protein] + NADH + H+
|
1.2.1.80
long-chain acyl-[acyl-carrier-protein] reductase
|
–
|
|
|
MetaCyc:
RXN-11706_WOP
|
|
|
|
palmitoyl-[acyl-carrier_protein] + malonyl-CoA <=> 1-heptadecene + CO2 + [acyl-carrier_protein] + CoA
|
2.3.1
|
–
|
|
|
MetaCyc:
RXN-13258
|
|
|
|
palmitoyl-[acyl-carrier_protein] + reduced_flavodoxin + O2 <=> pimeloyl-[acyl-carrier_protein] + an_n-alkanal + flavin + H2O + H+
|
1.14.14.46
pimeloyl-[acyl-carrier protein] synthase
|
–
|
M
|
|
MetaCyc:
RXN-13834
|
|
|
|
palmitoyl-[acyl-carrier_protein] + reduced_flavodoxin + O2 <=> 7-hydroxy-long-chain_acyl-[acp] + flavin + H2O
|
not assigned
|
–
|
|
|
MetaCyc:
RXN-13835
|
|
|
|
palmitoyl-[acyl-carrier_protein] + 1-stearoyl-sn-glycerol_3-phosphate <=> 1-stearoyl-2-palmitoyl-sn-glycerol_3-phosphate + [acyl-carrier_protein]
|
2.3.1.51
1-acylglycerol-3-phosphate O-acyltransferase
|
–
|
|
|
MetaCyc:
RXN-16025
|
|
|
|
palmitoyl-[acyl-carrier_protein] + commendamide <=> N-[(3-palmitoyloxy)-palmitoyl]glycine + [acyl-carrier_protein]
|
2.3.1
|
–
|
M
|
|
MetaCyc:
RXN-20867
|
|
|
|
palmitoyl-[acyl-carrier_protein] + reduced_ferredoxin_[iron-sulfur]_cluster + O2 + H+ <=> (4Z)-hexadec-4-enoyl-[acp] + oxidized_ferredoxin + H2O
|
1.14.19.11
acyl-[acyl-carrier-protein] 4-desaturase
|
–
|
M
|
|
MetaCyc:
RXN-8390
|
|
|
|
palmitoyl-[acyl-carrier_protein] + 1-palmitoyl-sn-glycerol_3-phosphate <=> 1,2-dipalmitoyl-sn-glycerol_3-phosphate + [acyl-carrier_protein]
|
2.3.1.51
1-acylglycerol-3-phosphate O-acyltransferase
|
–
|
|
|
MetaCyc:
RXN0-6705
|
|
|
|
dATP + fatty_acid + [acyl-carrier_protein] <=> dAMP + diphosphate + palmitoyl-[acyl-carrier_protein]
|
6.2.1.20
long-chain-fatty-acid---[acyl-carrier-protein] ligase
|
–
|
|
|
BRENDA:
BS210
|
|
|
|
palmitoyl-[acyl-carrier_protein] + reduced_flavodoxin + O2 <=> 11-hydroxyhexadecanoyl-[acyl-carrier_protein] + 12-hydroxyhexadecanoyl-[acyl-carrier_protein] + 13-hydroxytetradecanoyl-[acyl-carrier_protein] + 14-hydroxytetradecanoyl-[acyl-carrier_protein] + 15-hydroxytetradecanoyl-[acyl-carrier_protein] + flavin + H2O
|
1.14.14.46
pimeloyl-[acyl-carrier protein] synthase
|
–
|
|
|
BRENDA:
BS423669
|
|
|
|
palmitoyl-[acyl-carrier_protein] + reduced_ferredoxin + O2 + H+ <=> 9-hexadecenoyl-[acyl-carrier_protein] + oxidized_ferredoxin + H2O
|
1.14.19.2
stearoyl-[acyl-carrier-protein] 9-desaturase
|
–
|
|
|
BRENDA:
BS451377
|
|
|
|
palmitoyl-[acyl-carrier_protein] + reduced_ferredoxin + O2 + H+ <=> 9-octadecenoyl-[acyl-carrier_protein] + oxidized_ferredoxin + H2O
|
1.14.19.2
stearoyl-[acyl-carrier-protein] 9-desaturase
|
–
|
|
|
BRENDA:
BS451378
|
|
|
|
palmitoyl-[acyl-carrier_protein] + reduced_acceptor + O2 <=> palmitoleoyl-[acyl-carrier_protein] + A + H2O
|
1.14.19.2
stearoyl-[acyl-carrier-protein] 9-desaturase
|
–
|
|
|
BRENDA:
BS389516
|
|
|
|
stearoyl-[acyl-carrier_protein] + sn-3-D-galactosyl-sn-2-acylglycerol <=> palmitoyl-[acyl-carrier_protein] + monogalactosyldiacylglycerol
|
2.3.1.141
galactosylacylglycerol O-acyltransferase
|
–
|
|
|
BRENDA:
BS320511
|
|
|
|
2-hexadecenoyl-[acyl-carrier_protein] + NADH <=> palmitoyl-[acyl-carrier_protein] + NAD+
|
1.3.1.9
enoyl-[acyl-carrier-protein] reductase (NADH)
|
–
|
|
|
BRENDA:
BS258655
|
|
|
|
palmitoyl-[acyl-carrier_protein] + NADH + H+ <=> octadecanal + [acyl-carrier_protein] + NAD+
|
1.2.1.80
long-chain acyl-[acyl-carrier-protein] reductase
|
–
|
|
|
BRENDA:
BS413382-a
|
|
|
|
palmitoyl-[acyl-carrier_protein] + phosphate <=> hexadecanoyl_phosphate + [acyl-carrier_protein]
|
2.3.1.274
phosphate acyltransferase
|
–
|
|
|
BRENDA:
BS454458
|
|
|
|
palmitoyl-[acyl-carrier_protein] + phosphate <=> octadecanoyl_phosphate + [acyl-carrier_protein]
|
2.3.1.274
phosphate acyltransferase
|
–
|
|
|
BRENDA:
BS445765
|
|
|
|
palmitoyl-[acyl-carrier_protein] + dodecanoyl-Kdo2-lipid_IVA <=> dodecanoyl-(hexadecanoyl)-Kdo2-lipid_IVA + [acyl-carrier_protein]
|
2.3.1.243
lauroyl-Kdo2-lipid IVA myristoyltransferase
|
–
|
|
|
BRENDA:
BS455763
|
|
|
|
palmitoyl-[acyl-carrier_protein] + NADPH + H+ <=> octadecanal + [acyl-carrier_protein] + NADP+
|
1.2.1.80
long-chain acyl-[acyl-carrier-protein] reductase
|
–
|
|
|
BRENDA:
BS413382
|
|
|
|
palmitoyl-[acyl-carrier_protein] + reduced_acceptor + O2 <=> (4Z)-hexadec-4-enoyl-[acyl-carrier_protein] + acceptor + H2O
|
1.14.19.11
acyl-[acyl-carrier-protein] 4-desaturase
|
–
|
|
|
BRENDA:
BS432893
|
|
|
|
palmitoyl-[acyl-carrier_protein] + reduced_acceptor + O2 <=> 6-hexadecenoyl-[acyl-carrier_protein] + acceptor + H2O
|
1.14.19.3
acyl-CoA 6-desaturase
|
–
|
|
|
BRENDA:
BS287988
|
|
|
|
palmitoyl-[acyl-carrier_protein] + reduced_acceptor + O2 <=> 9-hexadecenoyl-[acyl-carrier_protein] + acceptor + H2O
|
1.14.19.2
stearoyl-[acyl-carrier-protein] 9-desaturase
|
–
|
|
|
BRENDA:
BS287985
|
|
|
|
palmitoyl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] <=> 3-oxooctanoyl-[acyl-carrier_protein] + CO2 + [acyl-carrier_protein]
|
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
|
–
|
|
|
BRENDA:
BS377478
|
|
|
|
palmitoyl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] <=> 3-oxoeicosanoyl-[acyl-carrier_protein] + CO2 + [acyl-carrier_protein]
|
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
|
–
|
|
|
BRENDA:
BS320876
|
|
|
|
palmitoyl-[acyl-carrier_protein] + malonyl-CoA <=> 3-oxooctadecanoyl-[acyl-carrier_protein] + CO2 + CoA
|
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
|
–
|
B
|
|
BRENDA:
BS320882
|
|
|
|
palmitoyl-[acyl-carrier_protein] + lysophosphatidic_acid <=> [acyl-carrier_protein] + 1-acyl-2-palmitoyl-sn-glycerol_3-phosphate
|
2.3.1.51
1-acylglycerol-3-phosphate O-acyltransferase
|
–
|
|
|
BRENDA:
BS456241
|
|